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Global and local thermodynamic equilibrium do not prescribe the specific form of a real thermodynamic system, for example, the atomic constitution of a real thermodynamic element such as a solid. The form of that element might be ionic, metallic, metallic oxides, semiconductor, ferroelectric, ferromagnetic, ferrimagnetic, antiferromagnetic, ionic solids, or molecular.[35] Thermodynamics requires the existence of at least one thermodynamic state, but what actually is that state? In thermodynamic models, a state is defined by a set of properties of a particular thermodynamic element and by a particular number of non-thermodynamic variables. The properties of the element may be described by its molar mass, its atom type, the distribution of the masses of the individual atoms, the concentration of the elements in the solid, and many other properties.[36] The number of non-thermodynamic variables may be described by a particular number of necessary conditions, that is, the conditions for composition of the element with this filler and the conditions for its bulk density, or the number of independent variables determining the value of all the properties of the element.[37] Thermodynamic theory also requires the existence of a minimum number of constraints.[38] Elements of some thermodynamic elements might not be uniquely identified by any set of properties. For example, a certain element might be a mixture of, say, hydrogen and carbon, and there might be two different sets of properties that are completely equivalent. Thermodynamically, such elements have only one thermodynamic state. Some atoms and molecules may have two, or even more, distinct types of state, as, for example, one type of metallic state and another state in which all the metals are in a non-metallic state.[39] It is possible to describe a phase transition from one state to another by considering that the properties of the element are being described by some values and the properties are being changed by the presence of the other state. The other state becomes more predominant, and the properties of the element change with respect to the values of the other state. Inert-solvent and liquid-solvent phase transition examples, phase transitions between different crystal structures, and phase transitions in the ab-crystalline structure of some metals in which the metal atoms lose their properties and become a metallic lattice are all examples of phase transitions that employ the above description.[40] d2c66b5586
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